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Help links for
OCR Advanced Level Chemistry A Courses (AS level and the full A level chemistry
course A)
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INDEX of subject
content based on the OCR A and AS advanced level chemistry
syllabus A
Modules 1-4 are for both OCR AS and A level chemistry
Module 1 – Development of practical
skills in chemistry (for OCR AS level and A level chemistry
A)
1.1 Practical
skills assessed in a written examination
1.2
Practical
skills assessed in the practical endorsement (A level
chemistry only)
Module 2 – Foundations in chemistry
(for OCR AS level and A level chemistry A)
2.1
Atoms and
reactions (for OCR AS level and A level chemistry A)
2.1.1
Atomic
structure and isotopes
2.1.2
Compounds,
formulae and equations
2.1.3
Amount of
substance
2.1.4
Acids
2.1.5
Redox
2.2
Electrons,
bonding and structure (for OCR AS level and A level chemistry
A)
2.2.1
Electron
structure
2.2.2
Bonding and
structure
Module 3 – Periodic table and energy
(for OCR AS level and A level chemistry A)
3.1
The periodic
table (for OCR AS level and A level chemistry A)
3.1.1
Periodicity
3.1.2
Group 2
3.1.3
The halogens
3.1.4
Qualitative
analysis
3.2.1
Enthalpy
changes
3.2.2
Reaction rates
3.2.3
Chemical
equilibrium (qualitative)
Module 4 – Core organic chemistry
(for OCR AS level and A level chemistry A)
4.1
Basic concepts
and hydrocarbons (for OCR AS level and A level chemistry A)
4.1.1
Basic concepts
of organic chemistry
4.1.2
Alkanes
4.1.3
Alkenes
4.2
Alcohols,
haloalkanes and analysis (for OCR AS level and A level
chemistry A)
4.2.1
Alcohols
4.2.2
Haloalkanes
4.2.3
Organic
synthesis
4.2.4
Analytical
techniques
Modules 5-6 are for OCR A level chemistry only
Module 5 – Physical chemistry and
transition elements (for OCR A level chemistry A only)
5.1
Rates, equilibrium and pH (for OCR AS level and A level
chemistry A)
5.1.1
How fast
5.1.2
How far
5.1.3
Acids, bases
and buffers
5.2
Energy
(for OCR AS level and A level chemistry A)
5.2.1
Lattice
enthalpy
5.2.2
Enthalpy and
entropy
5.2.3
Redox and
electrode potentials
5.3
Transition
elements
5.3.1
Transition
elements
5.3.2
Qualitative
analysis
Module 6 – Organic chemistry and
analysis (for OCR A level chemistry A only)
6.1.1
Aromatic
compounds
6.1.2
Carbonyl
compounds
6.1.3
Carboxylic
acids and esters
6.2
Nitrogen
compounds, polymers and organic synthesis
6.2.1
Amines
(for OCR AS level and A level chemistry A)
6.2.2
Amino acids,
amides and chirality
6.2.3
Polyesters and
polyamides
6.2.4
Carbon-carbon
bond formation
6.2.5
Organic
synthesis
6.3
Analysis
(for OCR AS level and A level chemistry A)
6.3.1
Chromatography
and qualitative analysis
6.3.2
Spectroscopy
INDEX of help links
based on the
OCR A and AS advanced level chemistry
syllabus A
Modules 1-4 are for both OCR AS and A level chemistry
Module 1 – Development of practical
skills in chemistry (for OCR AS level and A level chemistry A)
1.1 Practical
skills assessed in a written examination
1.2 Practical
skills assessed in the practical endorsement (A only?)
How to do acid-alkali
titration calculations, diagrams of apparatus, details of procedures
Introduction to chemical testing and analysing substances
Qualitative tests to identify organic molecule functional
groups of homologous series
TESTS for
Metal cations (positive ions), metal carbonates, ammonium ion, hydrogen ions (acids)
TESTS for Gases,
water and non–metallic elements
TESTS for Anions (negative ions) including hydroxide
(alkalis)
Module 2 – Foundations in chemistry
(for OCR AS level and A level chemistry A)
2.1
Atoms and reactions
(for OCR AS level and A level chemistry A)
2.1.1
Atomic structure and isotopes
Revision notes on all you need to know on ATOMIC
STRUCTURE for advanced level
What is relative atomic mass?,
relative isotopic mass and calculating relative atomic mass
Calculating relative
formula/molecular mass of a compound or element molecule
The Mass Spectrometer
and basics of mass spectrometry of elements
2.1.2 Compounds, formulae and equations
How to write
equations, work out formula and name compounds
Important
Some basic formulae,
salt solubility and water of crystallisation
2.1.3
Amount of substance (for OCR AS level and A level chemistry A)
What is relative atomic mass?,
relative isotopic mass and calculating relative atomic mass
Calculating relative
formula/molecular mass of a compound or element molecule
Introducing moles: The connection between moles, mass and formula mass - the basis of reacting mole ratio calculations
Calculations based on the
Avogadro Constant plus
Answers
Moles and the molar volume of a gas, Avogadro's Law
Reacting gas volume
ratios, Avogadro's Law
and Gay-Lussac's Law (ratio of gaseous
reactants-products)
Molarity, volumes and solution
concentrations (and diagrams of apparatus)
Gas calculations involving PVT relationships,
Boyle's and Charles Laws
Using
moles to calculate empirical formula and deduce molecular formula of a compound/molecule
(starting with reacting masses or % composition)
% reaction yield and theoretical yield calculations
and why you can't get 100% yield in practice
Determination and calculation of water of crystallisation
2.1.4 Acids
(for OCR AS level and A level chemistry A)
Basic notes and equations on acids, bases, salts,
uses of
acid-base titrations - upgrade from GCSE!
How to
do volumetric titration calculations e.g. acid-alkali titrations
(and diagrams of apparatus)
Part 1
Acid-base and other non-redox titration calculation questions
PART 1
Fully worked out Question Answers
Part 2
Acid-base and other non-redox titration calculation questions
PART 2 Fully
worked out Question Answers
2.1.5
Redox (for OCR AS
level and A level chemistry A)
Basic redox definitions, Introducing oxidation state (with sub–index)
and oxidation state rules–guidelines & inorganic examples
Using oxidation states to describe
redox changes in inorganic reactions (with sub–index)
2.2
Electrons, bonding and structure
2.2.1
Electron structure
Electronic Structure
Electron configurations of elements (Z = 1
to 56), ions and the
Periodic Table
2.2.2 Bonding and structure
(for OCR AS level and A level chemistry A)
Lots of
stuff
on bonding and the properties of the various resulting structures
Part 1
Introduction to chemical bonding - why? how? and
patterns
Part 2
Ionic Bonding: compounds and properties
Part 3
Covalent Bonding: small molecules
and properties
Part 4
Giant covalent structures and other big
molecules
Part 5
Metallic Bonding – structure and properties of metals
Introduction -
VSEPR theory for shapes of molecules - lots of inorganic
molecule/ion examples
Electronegativity and bond polarity
related to type of chemical
bonding
Introduction to intermolecular forces -
intermolecular bonding
Evidence & theory for hydrogen bonding in
covalent hydrides, importance in other
molecules
Module 3 – Periodic table and energy
(for OCR AS level and A level chemistry A)
3.1
The periodic table
Historical
Introduction to the modern periodic table and the nuclear physics origin of
elements
Electronic Structure of atoms - s p d f orbitals - electronic
basis of periodic table
Electron configurations of elements (Z = 1
to 56), ions and the
Periodic Table
Spectroscopy, hydrogen spectrum, evidence of quantum
levels, ionisation energy
patterns
3.1.1
Periodicity (for OCR
AS level and A level chemistry A)
Period 2 trends and explanations of
physical properties
Period 3 trends & explanations of physical properties
Periodicity graphs for
elements Z = 1 to 20. Period 1 to start of Period 4
Important trends down Groups
3.1.2
Group 2 (for OCR
AS level and A level chemistry A)
s-block
elements: Group 2 Alkaline Earth Metals -
Introduction and INDEX (several pages)
Basic redox definitions, oxidation
state and examples and simple redox equations
3.1.3
The halogens
The Group 7/17 The Halogens -
introduction and INDEX
(several pages)
3.1.4
Qualitative analysis
(for OCR AS level and A level chemistry A)
TESTS for
Metal cations (positive ions), metal carbonates, ammonium ion, hydrogen ions (acids)
TESTS for Anions (negative ions) including hydroxide
(alkalis)
3.2.1
Enthalpy changes (for
OCR AS level and A level chemistry A)
Basic notes of exothermic and endothermic
reactions and calculation of enthalpy changes from 'simple' calorimetry
experiments and resulting data
Thermochemistry - Calorimetry experiments -
Enthalpies of reaction, formation, combustion and bond dissociation
are explained with exemplar calculations
More advanced Introduction to enthalpy changes - reaction,
formation, combustion
Thermochemistry - Hess's Law and Enthalpy
Calculations - reaction, combustion, formation etc.
Bond Enthalpy Calculations
Experimental methods
for determining enthalpy changes and treatment of results
3.2.2
Reaction rates (basic
kinetics)
GCSE
level notes for the basics of rates of reactions
The
Maxwell-Boltzmann distribution of molecular kinetic energies (relate to
temperature & catalyst factors)
Heterogeneous
and homogeneous catalysis
3.2.3
Chemical equilibrium (qualitative)
Starter GCSE
level notes-reversible reactions-equilibrium
Part 1.
Equilibria Part 1. Dynamic molecular equilibrium and Le Chatelier's principle
Part 2.
Kc equilibrium expressions
and calculations
Part 3.
Equilibrium and
industrial processes
Module 4 – Core organic chemistry
(for OCR AS level and A level chemistry A)
4.1
Basic concepts and hydrocarbons
4.1.1
Basic concepts of organic chemistry
Summary index of organic nomenclature notes
(for OCR AS level and A level chemistry A)
The molecular
structure and naming of alkanes
The molecular structure and naming of
alkenes
The molecular structure and naming of haloalkanes
The molecular structure and naming of aliphatic
alcohols
The
molecular structure and naming of aldehydes and ketones
The molecular structure and naming of
carboxylic acids and derivatives
The classification,
structure and naming of
organic nitrogen compounds
Other
important ideas in organic chemistry
A summary of
homologous series, functional group names and structure in organic chemistry
General introduction and definition
of isomerism, structural isomerism - chain, positional, functional
group
An
Introduction to organic chemical reaction mechanisms and technical
terms explained
4.1.2 Alkanes (for OCR AS level and A
level chemistry A)
1.0
The chemistry of ALKANES and the petrochemical
industry
revision notes INDEX
1.1
The Molecular Structure and Nomenclature of Alkanes
1.2
Fractional distillation of crude
oil and uses of products
1.3
Modification of alkanes by
cracking, isomerisation and reforming
1.4
Complete and incomplete
combustion of alkanes and environmental pollution
1.5
Modification of hydrocarbon fuel mixtures, alternative fuels
and global warming
1.6
Chlorination and bromination of
alkanes, reaction mechanisms and uses of products
Combined
multiple choice and type in name quiz on the structure
and naming of alkanes
Matching pair quiz on hydrocarbon structure
4.1.3
Alkenes (for OCR AS level
and A level chemistry A)
INDEX of
ALL advanced revision notes on ALKENES
Revision notes on the structure and naming of ALKENES (including
cyclo..), including many isomers
STEREOISOMERISM general definition, E/Z (geometric/geometrical
cis/trans) isomerism
Bonding in alkenes, reactivity compared to alkanes,
electrophilic addition reaction with hydrogen halides
The electrophilic addition reaction
of alkenes with halogens (non-aqueous and aqueous conditions)
The reaction of alkenes with steam -
addition of water - synthesis of alcohols and the reaction of
alkenes with concentrated sulfuric acid
Reaction of alkenes with
hydrogen - uses of hydrogenation, structure and properties of oils
and fats
The
polymerisation of alkenes to
form addition polymers - structure, properties, uses of
poly(alkene) polymers
More on the
uses of plastics, issues with using plastics, solutions and recycling
methods
4.2
Alcohols, haloalkanes and analysis
4.2.1
Alcohols (for OCR AS
level and A level chemistry A)
INDEX of all revision notes on
ALCOHOLS (and mention of ethers)
Revision notes on the structure and naming
(nomenclature) of aliphatic
ALCOHOLS, ETHERS, epoxy-alkanes (parts 1-2), including isomers
The laboratory synthesis and manufacture of
alcohols
The reaction of alkenes with steam -
addition of water - synthesis of alcohols and the reaction of
alkenes with concentrated sulfuric acid
Physical properties
(boiling points, solubility) and intermolecular forces
Combustion of alcohols,
enthalpies of combustion and use as fuels
Controlled oxidation
of alcohols with selected oxidising
agents
Dehydration of alcohols and use of alkenes
Halogenation with hydrogen halides: Conversion of
alcohols to
halogenoalkanes (haloalkanes)
4.2.2
Haloalkanes (for OCR AS
level and A level chemistry A)
INDEX of
ALL revision notes on HALOGENOALKANES (haloalkanes)
Molecular Structure and Nomenclature of
Halogenoalkanes (haloalkanes)
Reactivity trends of halogenoalkanes - introduction to their nucleophilic
substitution reactions, the substitution reaction between halogenoalkanes (haloalkanes)
& water, experiments with silver nitrate solution
The
substitution reaction of halogenoalkanes (haloalkanes) with sodium/potassium hydroxide to
give alcohols
The chemistry of ozone depletion and how this environmental problem
was solved
4.2.3
Organic synthesis (for
OCR AS level and A level chemistry A)
You need a good
knowledge of all the synthesis reactions mentioned so far in modules 1-4 and
know how to work out a 1 or 2 stage synthesis i.e. know your starting
chemicals, reagents and reaction conditions.
4.2.4
Analytical techniques
(for OCR AS level and A level chemistry A)
INDEX of mass spectroscopy notes: mass spectra of organic
compounds, examples explained
INDEX of infrared spectroscopy notes: infrared spectra of organic compounds, examples explained
paper and thin layer
chromatography.
Instrumental Methods of Chemical Analysis
Applications of mass
spectrometry - linked to chromatography
Modules 5-6 are for OCR A level chemistry only
Module 5 – Physical chemistry and
transition elements (for OCR A level chemistry A only)
5.1
Rates, equilibrium and pH
5.1.1
How fast
(for OCR A level chemistry A only)
Obtaining rate data,
interpreting data, deducing orders of reaction and rate expressions
The Arrhenius
equation and calculating the activation energy Ea from kinetics–rates data
Kinetics versus thermodynamic stability
and reaction feasibility
Hydrolysis of halogenoalkanes
(see also nucleophilic substitution by
water/hydroxide ion)
5.1.2
How far (for OCR A
level chemistry A only)
Kc and Kp equilibrium expressions and
calculations
Equilibrium and
industrial processes
5.1.3
Acids, bases and buffers
(for OCR A level chemistry A only)
Equilibria: Bronsted-Lowry acid-base theories
Self-ionisation of water and pH scale
Strong acids - examples and pH calculations
Weak acids - examples & pH, Ka and pKa calculations
Acid-base indicator theory, pH curves and
titrations
Buffers - definition, formulation
and action
Buffer calculations
Case studies
of buffer function
5.2
Energy (for OCR A
level chemistry A only)
5.2.1
Lattice enthalpy
The
Born-Haber Cycle
5.2.2
Enthalpy and entropy (for
OCR A level chemistry A only)
Introduction to Entropy
Examples of
entropy values and comments
ΔS, Entropy changes and the
feasibility of a chemical change
More on ΔG, Free energy changes, feasibility and
applications
5.2.3
Redox and electrode potentials
(for OCR A level chemistry A only)
Redox Part 1
Basic redox definitions, oxidation
state and examples, simple redox equations
Redox Part 2
Analysing and constructing full inorganic redox
equations
Redox titration
calculation questions
FULL ANSWERS
and WORKING for REDOX TITRATION QUESTIONS
Redox equilibria, half-cell
reactions and electrode potentials
Simple cells notation and construction
The hydrogen electrode and standard conditions
Half-cell potentials, Electrochemical Series and using Eθcell for reaction feasibility
Electrochemical cells ('batteries') and fuel cell systems
5.3
Transition elements
(for OCR A level chemistry A only)
5.3.1
Transition elements
Introduction to the 3d-block, Transition Metals and
Data (full index)
3d block Transition Metals - Complexes
& ligands
3d block Transition Metals - Complexes and isomerism
3d block Transition Metals - Electron configuration
and colour theory
3d block Transition Metals - Catalysis
3d block transition metals - Hydroxide complex precipitate 'pictures',
formulae and equations
3d block Transition Metals - Hydrated salts, acidity of
hexa-aqua ions
Selected examples of
transition metal chemistry
(for OCR A level chemistry A only)
Chemistry of 3d block transition
metals - Chromium
Chemistry of 3d block transition
metals - Manganese
Chemistry of 3d block transition
metals - Iron
Chemistry
of 3d block transition metals - Cobalt
Chemistry of 3d block transition
metals - Nickel
Chemistry of 3d block transition
metals - Copper
Chemistry of other Transition Metals e.g. Ag and Pt
5.3.2
Qualitative analysis
(for OCR A level chemistry A only)
TESTS for
Metal cations (positive ions), metal carbonates, ammonium ion, hydrogen ions (acids)
TESTS for Anions (negative ions) including hydroxide
(alkalis)
Module 6 – Organic chemistry and
analysis (for OCR A level chemistry A only)
6.1.1
Aromatic compounds
(for OCR A level chemistry A only)
INDEX of all AROMATIC COMPOUND chemistry
revision notes
The Structure
& Naming of Aromatic Compounds,
including nomenclature of isomers
Proof of the structure of benzene, aromaticity
and electrophilic reactivity in arenes
Electrophilic substitution -
nitration of benzene /methylbenzene, properties and uses of
nitro-aromatics
Electrophilic substitution - ring
halogenation of benzene & methylbenzene, properties & uses of aryl
halides
Electrophilic substitution -
alkylation of arenes to give other arenes
Electrophilic substitution -
acylation of arenes, properties and uses of
aromatic ketones
The physical and chemical
properties of phenol and some of its derivatives and their uses
6.1.2
Carbonyl compounds (for
OCR A level chemistry A only)
INDEX of
ALL revision notes on ALDEHYDES and KETONES
Revision notes on the
Structure and Naming of Aldehydes and Ketones
The structure and reactivity of
aldehydes and ketones and nucleophilic addition of hydrogen cyanide
(also includes the hydrolysis of the
resulting nitriles to carboxylic acids)
The oxidation of aldehydes and
ketones, link with chemical tests
The reduction of aldehydes and
ketones with NaBH4
and LiAlH4 and
reduction of nitriles
Qualitative tests to identify organic molecule functional
groups of homologous series
6.1.3
Carboxylic acids and esters
(for OCR A level chemistry A only)
INDEX of all revision notes on
CARBOXYLIC ACIDS and DERIVATIVES
Structure and naming of
carboxylic acids and derivatives
Physical properties of
carboxylic acids - trends discussed & explained (mpts, bpts,
solubility, odours!)
The weakly acidic nature and general reactions of carboxylic acids acting as
acids
Preparation & reactions of acid chlorides with water, alcohols,
ammonia, amines & mechanisms
Esters
- preparation, reactions including hydrolysis and
transesterification, uses
Natural esters - triglyceride fats and oils,
manufacture of margarine and biodiesel
6.2
Nitrogen compounds, polymers and organic synthesis
6.2.1
Amines (for OCR A
level chemistry A only)
INDEX of all ORGANIC NITROGEN COMPOUND chemistry pages
Structure, Classification
& Naming of
Organic Nitrogen Compounds
The
structure, classification and physical properties of aliphatic amines
Methods of synthesising amines
(aliphatic and aromatic)
6.2.2
Amino acids, amides and chirality
(for OCR A level chemistry A only)
Amino acids - molecular
structure, preparation and reactions - two functional group
chemistries
Protein-enzyme structure, function
and inhibition
Protein
analysis and synthesis
Amine
bases and the hydrogen bonding in DNA and RNA
Amides
- molecular structure, physical properties, preparations, reactions, brief mention of
polyamides
Stereoisomerism - R/S Optical
Isomerism examples and chiral auxiliary synthesis
6.2.3 Polyesters and polyamides
(for OCR A level chemistry A only)
polyamides - formation, structure, properties and uses
The manufacture, molecular structure, properties and uses of
polyesters
Polymerisation of alkenes to
form addition polymers - structure, properties, uses
6.2.4
Carbon-carbon bond formation
(for OCR A level chemistry A only)
The
nucleophilic substitution reaction between halogenoalkanes (haloalkanes) and potassium cyanide
and hydrolysis of nitriles to carboxylic acids
The structure and reactivity of
aldehydes and ketones and nucleophilic addition of hydrogen cyanide
and hydrolysis of the
resulting nitriles to carboxylic acids
Methods of synthesising amines
(aliphatic and aromatic), including reaction of amines with halogenoalkanes
and reduction of nitriles
6.2.5
Organic synthesis
You need a good
knowledge of all the synthesis reactions mentioned in the syllabus and know
how to work out a 1 or 2 or 3? stage synthesis i.e. know your starting
chemicals, reagents and reaction conditions.
6.3
Analysis (for OCR A
level chemistry A only)
6.3.1
Chromatography and qualitative analysis
paper and thin layer
chromatography.
Instrumental Methods of Chemical Analysis
including gas chromatography
Applications of mass
spectrometry - linked to chromatography
Qualitative Analysis Tests for organic functional groups
notes
(use alphabetical index)
6.3.2
Spectroscopy (NMR) (for
OCR A level chemistry A only)
INDEX of nuclear magnetic resonance
spectroscopy: 1H NMR spectra of organic
compounds
INDEX of nuclear magnetic resonance
spectroscopy: 13C NMR spectra of organic
compounds
and, previously
encountered
Applications of mass
spectrometry - linked to chromatography
INDEX of mass spectroscopy notes: mass spectra of organic
compounds, examples explained
INDEX of infrared spectroscopy notes: infrared spectra of organic compounds, examples explained
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Revision notes
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help links based on the syllabus for the OCR A level and AS level
advanced level chemistry A course, a study guide to the topics in OCR A
level and AS level advanced level chemistry A, help with mock exam revision
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