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Advanced Organic Chemistry: Carbon-13 NMR spectrum of ethoxyethane

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The Carbon-13 NMR spectrum of ethoxyethane (diethyl ether)

Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing C-13 NMR spectra of ethoxyethane

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C-13 NMR spectroscopy - spectra index

C-13 nmr spectrum of ethoxyethane analysis of chemical shifts ppm interpretation of C-13 chemical shifts ppm of ethoxyethane doc brown's advanced organic chemistry revision notes 

TMS is the acronym for tetramethylsilane, formula Si(CH3)4, whose 13C atoms are arbitrarily given a chemical shift of 0.0 ppm. This is the 'standard' in 13C NMR spectroscopy and all other 13C shifts, called chemical shifts, depend on the individual (electronic) chemical environment of the 13C atoms in an organic molecule - ethoxyethane Ethoxyethane C4H10O, alcohols and ether structure and naming (c) doc b , alcohols and ether structure and naming (c) doc b , alcohols and ether structure and naming (c) doc b

Interpreting the C-13 NMR spectrum of ethoxyethane (diethyl ether)

As you can see from the diagram above there are only 2 chemical shift lines in the C-13 NMR spectrum of ethoxyethane indicating only 2 different chemical environments of carbon atoms.

CH3CH2OCH2CH3

(note the colours indicating the two different chemical environment of the carbon atoms).


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