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Advanced Organic Chemistry: Infrared spectrum of 1-bromo-2-chloroethane

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Interpreting the infrared spectrum of 1-bromo-2-chloroethane

Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing infrared spectra of 1-bromo-2-chloroethane

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Infrared spectroscopy - spectra index

C2H4BrCl BrCH2CH2Cl infrared spectrum of 1-bromo-2-chloroethane wavenumbers cm-1 functional group detection fingerprint pattern identification of 1-bromo-2-chloroethane doc brown's advanced organic chemistry revision notes 

Spectra obtained from a liquid film of 1-bromo-2-chloroethane. The right-hand part of the of the infrared spectrum of 1-bromo-2-chloroethane, wavenumbers ~1500 to 400 cm-1 is considered the fingerprint region for the identification of 1-bromo-2-chloroethane and most organic compounds. It is due to a unique set of complex overlapping vibrations of the atoms of the molecule of 1-bromo-2-chloroethane.

1-bromo-2-chloroethaneC2H4BrClBrCH2CH2Cl

Interpretation of the infrared spectrum of 1-bromo-2-chloroethane

The most prominent infrared absorption lines of 1-bromo-2-chloroethane

Several moderately strong absorption bands at wavenumbers 2975 to 2845 cm-1 for C-H stretching vibrations - collectively give the impression of strong absorption in the infrared spectrum of 1-bromo-2-chloroethane.

Several strong absorption bands from C-H deformation vibrations at wavenumbers 1470 to 1370 cm-1.

Several strong absorption bands from 880 to 500 cm-1 due to the C-Cl and C-Br stretching vibrations of 1-bromo-2-chloroethane.

The absence of other specific functional group bands will show that a particular functional group is absent from the 1-bromo-2-chloroethane molecular structure.


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