Advanced Organic Chemistry: Mass spectrum of cyclohexane
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The mass spectrum of cyclohexane
Doc Brown's Chemistry Advanced Level Pre-University Chemistry Revision Study Notes for UK IB KS5 A/AS GCE advanced A level organic chemistry students US K12 grade 11 grade 12 organic chemistry courses involving molecular spectroscopy analysing mass spectra of cyclohexane
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Cyclohexane, C6H12 , , , all bond angles ~109o
Interpreting the fragmentation pattern of the mass spectrum of cyclohexane
[M]+ is the molecular ion peak (M) with an m/z of 84 corresponding to [C6H12]+, the original cyclohexane molecule minus an electron.
The small M+1 peak at m/z 85, corresponds to an ionised cyclohexane molecule with one 13C atom in it i.e. an ionised cyclohexane molecule of formula 13C12C5H12
Identifying the species giving the most prominent peaks (apart from M) in the fragmentation pattern of cyclohexane.
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