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Brown's Chemistry Clinic
WJEC GCE AS CHEMISTRY
WJEC Advanced Subsidiary Chemistry
(Welsh AS Chemistry
syllabus-specification)
1st draft of my
unofficial support links for the NEW WJEC GCE AS Advanced Subsidiary
Chemistry Course starting September 2008 My unofficial support for this
WJEC GCE AS Advanced Level Chemistry syllabus-Specification
Scroll down and each
module, topic or unit is linked to potentially
useful sections on this site
*
WJEC A2
chemistry *
WJEC GCSE science-CHEMISTRY *
READ
CAREFULLY PLEASE remember that despite the fact that my 'A
level' chemistry notes are far from complete, and as yet, do not even cover all
the basics, but I think there is enough to start an unofficial support page. By
clicking on the text and [ORGANIC],
[INORGANIC], [PHYSICAL-THEORETICAL]
and [useful UK based GCSE/IGCSE revision notes] icon
links you should find things to help on a particular topic. The
notes-quizzes are not just for your particular syllabus, but are
designed to cover, eventually, any Chemistry in UK based advanced level
pre-university chemistry specification so you need to pick out the bits which
are useful for your syllabus.
READ
CAREFULLY When you follow a link you will find some useful information on the web page
about the topic you are researching. Sometimes the link goes straight to the
relevant paragraph but otherwise use the sub-indexes of key words or headings at
the top of each page. To return to this
page you must click on the <== back on the browser link bar. All the syllabus-topic-unit titles
below are taken from the official syllabuses which you can download from the
appropriate site.
READ
CAREFULLY My advanced level chemistry pre-university research-information-revision notes
are ALL are being slowly revised and extended-updated
to cover any 'A level' chemistry BUT I do not have time to deliver extended
responses to email questions and please do NOT ask for past papers.
EMAIL
query?comment
WJEC GCE Advanced
Subsidiary Chemistry - Summary of AS Units and Contents Links
Unit CH1
Controlling and Using Chemical Changes:
(in order to make things,
produce energy and solve environmental problems):
Topic 1.1 Basic ideas on atoms * Topic 1.2
Chemical Calculations
Topic 2.1 Chemical equilibrium and acid-base reactions
* Topic 2.2 Energetics * Topic 2.3
Kinetics
Topic 3 Application of the principles studied in Unit 1 to
problems encountered in the production of chemicals and energy
Unit CH2 Properties,
Structure and bonding:
Topic 4.1 Chemical Bonding * Topic 4.2
Forces between molecules * Topic 4.3 Shapes of
molecules * Topic 4.4 Solubility of compounds in
water
Topic 5 Solid Structures
Topic 6.1 The Periodic Table * Topic 6.2
Trends in properties of the elements of the s-block and
Group 7 (17)
Topic 7.1 Organic compounds and their reactions *
Topic 7.2 Hydrocarbons * 7.3
Halogenoalkanes * Topic 7.4 Alcohols
Topic 8 Analytical Techniques

Unit
CH1 Controlling and Using Chemical Changes
(in order to make things,
produce energy and solve environmental problems)

Topic 1.1
Basic ideas on atoms (WJEC GCE AS Chemistry)
-
GCSE Atomic Structure Notes
including mass spectrometry of elements
- the structure of atoms, isotopes, nuclear structure notation,
'simple' electronic structure and the Periodic Table and mass spectrometry
for isotope analysis and calculation of relative atomic mass (Ar)
and measurement of molecular mass
-
Radioactivity and
Nuclear Power -
The structure of atoms
linked to the properties and uses of alpha, beta and gamma radiation,
radioisotope dating, half-life.
Sub-index and
keywords at top of page
-
Periodic Table Advanced Inorganic Chemistry Notes Part
2 "Electronic Structure and Ionisation Energies"
- Electron arrangements -
electron configurations and the Periodic Table - s, p, d and f blocks -
ionization energy patterns, section on hydrogen spectrum and emission
spectroscopy

Topic 1.2 Chemical
Calculations (WJEC GCE AS Chemistry)
-
GCSE Atomic Structure Notes
including mass spectrometry of elements
- the structure of atoms, isotopes, nuclear structure notation,
'simple' electronic structure and the Periodic Table and mass spectrometry
for isotope analysis and calculation of relative atomic mass (Ar)
and measurement of molecular mass
-

Chemical Calculations index - 1. to 16. sections of
explanation-examples and multiple choice and type in answer quizzes links
are built into the notes, designed up to higher
GCSE and basic GCE-AS/IB
calculations
-

section 1. Relative atomic mass (Ar)
and isotopic mass
-

section 2. Relative formula mass and relative molecular mass (Mr)
-

section 3. Law of Conservation of Mass and simple reacting mass calculations
-

section 4. % composition by mass of a compound
-
 section 5.
Empirical formula from reacting masses
-

section 6. Reacting masses of reactants and products and actual percent %
yield,
theoretical yield and atom economy
-
 section
7. Introducing moles - the connection of moles, mass and formula mass
-

section 8.
Using
moles to deduce empirical/molecular formula of a compound/molecule starting with
reacting masses or % composition by mass
-
 section 9. moles and
molar gas volume and Avogadro's Law
-

section 10.
Reacting gas volume
ratios, Avogadro's Law and
Gay-Lussac's Law
-

section 14. % actual and theoretical yield, dilution calculations, atom
economy, volumetric titration apparatus, water of crystallisation, how much
of reactants are needed?
(sub-index near top of page)

Topic 2.1 Chemical
equilibrium and acid-base reactions (WJEC GCE AS
Chemistry)
-
Starter GCSE
Notes on reversible reactions, equilibrium, ammonia synthesis
-
Advanced
Chemistry Equilibria Part 1.
Dynamic molecular equilibrium and Le Chatelier's principle
-
Equilibria Part 3
equilibrium and industrial processes
(can ignore the Kp/Kc equilibrium expressions and concentrate on the
application of Le Chatelier's Principle to industrial processes)
-
GCSE Notes on Acids, Bases, Alkalis, pH,
Neutralisation and Salts
- includes theory, lots of formulae and word and balanced symbol
equations, salt preparations and equations.
-
Extra
GCSE Aqueous Chemistry
Notes
- simple acid-base theory Sub-index at top of page
-

section 11. Making up solutions -
concentration & molarity
-

section 12. Volumetric acid-alkali titration easy calculations
- apparatus/analysis
-
Structured Question worksheet including acid-base volumetric titration calculations (answers)

Topic 2.2 Energetics
(WJEC GCE AS Chemistry)
-
Basic notes of exothermic and endothermic
reactions and calculation of enthalpy changes from 'simple' calorimetry
experiments and resulting data
-
GCSE Multiple choice quiz on Energy Changes in Chemical Reactions
-
Enthalpy and Bond Energy Calculation
Questions (answers)

Topic 2.3 Kinetics
(WJEC GCE AS Chemistry)
-
GCSE
Notes for the basics of rates of reactions - kinetics
-
KINETICS - advanced rates of reactions
revision notes: temperature effect and activation energy, homogeneous catalysts
and heterogeneous
catalysts, obtaining data, rate expressions and orders of reaction,
deducing orders of reaction
-
Extra GCSE Industrial Chemistry Notes
-
section 2. on enzymes
(keyword alphabetical index near top of the page)

Topic 3 Application of the
principles studied in Unit 1 to problems encountered in the production
of chemicals and energy
(WJEC GCE AS Chemistry)
-
Equilibria Part 3
equilibrium and industrial processes
(can ignore the Kp/Kc equilibrium expressions and concentrate on the
application of Le Chatelier's Principle to industrial processes)
-
Extra GCSE Industrial Chemistry Notes
-
section 2. on enzymes
(keyword alphabetical index near top of the page)
-
Ammonia synthesis, reversible reactions
and chemical equilibrium notes
- including reversible reactions, equilibrium theory, nitric acid
manufacture, reactions of ammonia and ammonium salts, fertiliser ammonium salt preparation, problems with over-use or
fertilisers.

Unit
CH2 Properties, Structure and bonding

Topic 4.1 Chemical Bonding
(WJEC GCE AS Chemistry)
-
Introduction to BONDING
-
Revision notes on the basics of Ionic BONDING
and an ionic lattice
-
Revision notes on the basics of
Covalent BONDING and small molecules and their properties
-
Revision notes on Inorganic redox reactions
- Part 1 includes introduction to electronegativity

Topic 4.2 Forces between
molecules (WJEC
GCE AS Chemistry)
Equilibria Part 8 Phase equilibria-vapour
pressure, includes discussion of organic molecule examples - bond polarity, boiling point and intermolecular forces

Topic 4.3 Shapes of
molecules (WJEC
GCE AS Chemistry)
-
Revision notes on shapes
and bond angles of simple molecules (VSEPR), ions, transition metal complexes and a section on
shape and bond angles in
organic molecules

Topic 4.4 Solubility of
compounds in water
(WJEC GCE AS Chemistry)
-
Water and
solubility curves for salts that form aqueous solutions

Topic 5 Solid
Structures (WJEC GCE AS Chemistry)
-
Revision notes on the basics of Ionic BONDING
and an ionic lattice
-
Revision notes on the basics of Covalent BONDING and giant structures and
their properties and uses
-
Revision notes on the basics of
Metallic BONDING, properties and uses of metals

Topic 6.1 The Periodic
Table (WJEC
GCE AS Chemistry)
-
GCSE Summary
notes of the Periodic Table
- A basic introduction: Explanation and overview of Groups, Periods, Series etc. with links to
more detailed notes on the Group 1 Alkali Metals, Group 7 Halogens, Group 0
Noble Gases and Transition Metals.
-
Periodic Table Advanced Inorganic Chemistry Notes Part 1 "Historical
Introduction" and the full modern periodic table
-
Periodic Table Advanced Inorganic Chemistry Notes Part
2 "Electronic Structure and Ionisation Energies"
- Electron arrangements -
electron configurations and the Periodic Table - s, p, d and f blocks -
ionization energy patterns, section on hydrogen spectrum and emission
spectroscopy
-
Periodic Table Notes Part 11: Compiled
tables of data on Groups 1-7,0 and 3d-block-Transition Metals
-
Data-periodicity graphs for
elements Z = 1 to 20 Period 1, Period 2, Period 3 and start of Period 4
-
periodicity
graph for elements Z = 1-38 Period 1, Period 2, Period 3, Period 4 and start
of Period 5
-
The Reactivity Series of Metals, Corrosion and includes
a simplified introduction to Redox
Reaction
-
Revision notes on Inorganic redox reactions
- Part 1 includes introduction to electronegativity, explaining oxidation and reduction reactions and oxidation
state/oxidation number changes

Topic 6.2 Trends in
properties of the elements of the s-block and Group 7 (17)
-
Group 1
The Alkali Metals Notes -
Tabulated element data for lithium,
sodium and potassium etc., physical and chemical properties of the metals,
group trends, reactions with water, oxygen and chlorine, theory of group
reactivity trend, compound formulae, uses of metals and compounds.
-
Periodic Table:
detailed Advanced Inorganic Chemistry Notes Part 7 Group 1 Alkali Metals and
Group 2 Alkaline Earth Metals - detailed revision notes
-
Groups 1-2 data-group trend graphs
-
Multiple choice Quiz on Group 1 Alkali Metals and Group 2 Alkaline Earth
Metals (easy start!)
-
Qualitative Analysis: Chemical
Identity Tests - anions e.g.
non-metal negative ions
(keyword alphabetical index at top of page)
-
Qualitative Analysis: Chemical
Identity Tests - cations e.g.
positive metal ions
(keyword alphabetical index at top of page)
-
Group 7 The Halogens - GCSE Notes
- data, physical properties and chemistry of elements chlorine, bromine,
iodine and their compounds, electrolysis of aqueous sodium chloride/brine
and the uses of the products - chlorine, hydrogen and sodium hydroxide.
Alphabetical keyword-phrase list at top of page.

Topic 7.1 Organic compounds and
their reactions (WJEC
GCE AS Chemistry)
-
Extra GCSE Organic Chemistry Notes - Alkane & alkene homologous
series 'families', alcohols like ethanol, other organic molecule families
e.g. carboxylic acids, esters, polymers, natural molecules - carbohydrates,
sugars, amino acids, proteins and cooking, natural fats & oils,
hydrogenation of fats, soaps, Vitamin C,
Drugs-analgesics, Food Additives and CFC's, Ozone layer and free radicals.
Use sub-index and keyword list at top of page and can be read as a basic
introductory view of what 'organic chemistry' is all about without the need
for too many concepts!
-
A summary of
homologous series, functional group names and structure in Organic Chemistry
(look for 'general formulae' and links to organic molecular structure and
nomenclature/naming pages)
-
Organic
Chemistry ISOMERISM general definition
(use sub-index at top of page)
-
Organic
Chemistry (1) STRUCTURAL ISOMERISM general
definition (use sub-index at top of
page)
-
Organic
Chemistry (1a) Chain isomerism (use sub-index at top of
page)
-
Organic
Chemistry (1a) Chain isomerism (Ex 1a.1 discusses alkane isomers,
intermolecular forces and boiling point)
-
Organic
Chemistry (1b) Positional isomerism (use sub-index at top of
page)
-
Organic
Chemistry (1c)
Functional group
isomerism (use sub-index at top of
page)
-
Organic
Chemistry (2)
STEREOISOMERISM general definition (use sub-index at top of
page)
-
Organic
Chemistry (2a) Geometrical Isomerism (use sub-index at top of
page)
-
Equilibria Part 8 has a section on intermolecular forces - bond polarity, boiling point
using organic molecules as examples
-

section 8.
Using
moles to deduce empirical/molecular formula of a compound/molecule starting with
reacting masses or % composition by mass
-
Organic synthesis
redox reactions - including oxidation of alcohols (use top summary table index)
-
MECHANISM
Introduction
and terms used in organic chemistry (on the mechanism pages the
type of reaction, basic reaction equations and conditions are quoted which may act as a
suitable reference, there is also a reaction index on each page)
-
Qualitative Analysis: Tests for organic
functional groups notes (use alphabetical index for homologous series,
reagents etc.) (alphabetical keyword index at top of page)

Topic 7.2 Hydrocarbons
(WJEC GCE AS Chemistry)
-
GCSE notes on Oil and useful
products -
The hydrocarbons from oil and their uses
e.g. fuels-combustion, cracking to make alkenes, simple addition reactions of alkenes
(bromine, hydrogen) and test for
alkenes,
polymers/uses of plastics, fossil fuels and environmental problems etc. See also
Alternative and Fossil Fuel
Survey
and Global
warming discussion
page.
-
Revision notes on the
structure & naming (nomenclature) of ALKANES (and
cycloalkanes) notes, including nomenclature of isomers
-
Multiple
choice
Quiz on the structure and naming (nomenclature) of alkanes
-
Type
in name Quiz on the structure & naming of ALKANES (and
nomenclature of cycloalkanes)
-
Quiz on aspects of "Development of Fuels"
-
Quiz on
aspects of the Petrochemical Industry
-
Alternative and Fossil Fuel Survey
-
Gas Preparation Ex 10 Laboratory paraffin cracking experiment
-
Revision notes on the structure & naming (nomenclature) of ALKENES (and
cycloalkanes) notes, including nomenclature of isomers
-
Multiple choice Quiz on the Structure and naming
(nomenclature) of ALKENES
-
Type in name Quiz on the
nomenclature of ALKENES
-
MECHANISM
Introduction
and terms used in organic chemistry (on the mechanism pages the
type of reaction, basic reaction equations and conditions are quoted which may act as a
suitable reference, there is also a reaction index on each page)
-
Mechanism
of the free radical
chlorination/bromination of alkanes to make halogenoalkanes
-
Mechanism
of the free radical
chlorination/bromination of alkanes to make halogenoalkanes
-
Mechanism
of electrophilic addition of
hydrogen bromide to alkenes
to make bromoalkanes (introduction and example of
electrophilic addition to alkenes) (includes reagents, reaction
conditions and exemplar balanced equations
showing product formation)
-
Mechanism
of electrophilic addition of bromine
to alkenes
with pure
bromine to make dibromoalkanes (includes
reagents, reaction conditions and exemplar balanced equations
showing product formation)
-
Mechanism:
Halogenoalkanes
(haloalkanes, alkyl halides)
Elimination of
hydrogen bromide to give an alkene (mechanism
NOT needed but includes
reagents, reaction conditions and exemplar balanced equations
showing product formation)

Topic 7.3 Halogenoalkanes
(WJEC GCE AS Chemistry)
-
Mechanism
of the free radical
chlorination/bromination of alkanes to make halogenoalkanes
-
Revision notes on the structure and naming of HALOGENOALKANES/HALOALKANES and
classification into primary (prim)/secondary (sec)/tertiary (tert)
(including nomenclature of many isomers
-
Multiple choice Quiz on the structure and naming
(nomenclature) of
HALOGENOALKANES (haloalkanes)
-
Type in name Quiz on the
nomenclature of HALOGENOALKANES (haloalkanes)
-
Extra GCSE Organic Chemistry Notes -
section 7. on CFC's, Ozone layer and free radicals
-
Mechanism: Halogenoalkanes
(haloalkanes/alkyl halides)
Nucleophilic substitution by water/hydroxide ion
[SN1 or SN2, hydrolysis to alcohol]
(introduction to, and example of, nucleophilic substitution in
halogenoalkanes)
(includes reagents, reaction conditions and exemplar balanced equations
showing product

Topic 7.4 Alcohols
(WJEC GCE AS Chemistry)
-
Revision notes on the structure and naming (nomenclature) of
aliphatic ALCOHOLS - Classification into primary (prim), secondary
(sec) and tertiary (tert) - notes include isomers and other related compounds
which may not be needed
-
Multiple choice Quiz on
the structure and naming (nomenclature) of aliphatic ALCOHOLS (includes ethers
which may not be needed)
-
Type in name Quiz on the nomenclature of aliphatic ALCOHOLS (includes ethers
which may not be needed)
-
Extra GCSE Organic Chemistry Notes
- introductory section on alcohols like ethanol
-
Mechanism:
Halogenoalkanes
(haloalkanes, alkyl halides)
Elimination of
hydrogen bromide to give an alkene (mechanism
NOT needed but includes
reagents, reaction conditions and exemplar balanced equations
showing product formation)
-
Organic synthesis
redox reactions - including oxidation of alcohols (use top summary table index)

Topic 8
Analytical Techniques (WJEC GCE AS Chemistry)
-
-

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