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Part 5 Metallic Bonding, Structure and Properties

Doc Brown's Science-Chemistry Chemical Bonding GCSE/IGCSE/AS/A2 O Level Revision Notes

Metallic bonding is described and the properties of metals are described and explained using the giant metal lattice structure model which is used to explain the physical properties of metals

Part 1 Introduction - why do atoms bond together? (I suggest you read 1st)

Part 2 Ionic Bonding - compounds and properties

Part 3 Covalent Bonding - small simple molecules and properties

Part 4 Covalent Bonding - macromolecules and giant covalent structures

Part 5 Metallic Bonding - structure and properties of metals (this page)

Part 6 More advanced concepts for advanced level chemistry (in preparation, BUT a lot on intermolecular forces (intermolecular bonding) in Equilibria Part 8)


topPart 5.  METALLIC BONDING - structure and properties of metals

metal bonding model element/alloys * physical properties of metals


(c) doc b BONDING IN METALS

  • (c) doc bTo explain the properties of metals like iron or sodium we need a more sophisticated picture than a simple particle model of atoms all lined up in close packed rows and layers.
  • A giant metallic lattice. The crystal lattice of metals consists of ions (NOT atoms) surrounded by a 'sea of electrons' forming another type of giant lattice.
  • The outer electrons (-) from the original metal atoms are free to move around between the positive metal ions formed (+).
  • These free or 'delocalised' electrons are the 'electronic glue' holding the particles together.
  • There is a strong electrical force of attraction between these free and mobile electrons (-) and the 'immobile' positive metal ions (+) and this is the metallic bond.
  • Metallic bonding is not directional like covalent bonding, it is like ionic bonding in the sense that the force of attraction between the positive metal ions and the mobile electrons acts in every direction about the fixed (immobile) metal ions.
  • Metals can become weakened when repeatedly stressed and strained. This can lead to faults developing in the metal structure called 'metal fatigue' or 'stress fractures'. If the metal fatigue is significant it can lead to the collapse of a metal structure. So it is important develop alloys which are well designed, well tested and will last the expected lifetime of the structure whether it be part of an aircraft (eg titanium aircraft frame) or a part of a bridge (eg steel suspension cables).

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 Explaining the physical properties of metals

  • This strong bonding generally results in dense, strong materials with high melting and boiling points.

    • Usually a relatively large amount of energy is needed to melt or boil metals. Energy changes for the physical changes of state of melting and boiling for a range of differently bonded substances are compared in a section of the Energetics Notes.

  • Metals are good conductors of electricity because these 'free' electrons carry the charge of an electric current when a potential difference (voltage!) is applied across a piece of metal eg copper wire in household wiring or electrical appliances.

  • Metals are also good conductors of heat. This is also due to the free moving electrons. Non-metallic solids conduct heat energy by hotter more strongly vibrating atoms, knocking against cooler less strongly vibrating atoms to pass the particle kinetic energy on. In metals, as well as this effect, the 'hot' high kinetic energy electrons move around freely to transfer the particle kinetic energy more efficiently to 'cooler' atoms.

  • Typical metals also have a silvery surface but remember this may be easily tarnished by corrosive oxidation in air and water.

  • Unlike ionic solids, metals are very malleable, they can be readily bent, pressed or hammered into shape. The layers of atoms can slide over each other without fracturing the structure (see below). The reason for this is the mobility of the electrons. When planes of metal atoms are 'bent' or slide the electrons can run in between the atoms and maintain a strong bonding situation. This can't happen in ionic solids.

  • For more on the properties and uses of metals see Transition Metals and Extra Industrial Chemistry pages and the note and diagram below.

 Note on Alloy Structure

(c) doc b

  1. Shows the regular arrangement of the atoms in a pure metal crystal and the white spaces show where the free electrons are (yellow circles actually positive metal ions).
  2. Shows what happens when the metal is stressed by a strong force. The layers of atoms can slide over each other and the bonding is maintained as the mobile electrons keep in contact with atoms, so the metal remains intact BUT a different shape.
  3. Shows an alloy mixture. It is NOT a compound but a physical mixing of a metal plus at least one other material (shown by red circle), it can be another metal e.g. Ni, a non-metal e.g. C or a compound of carbon or manganese, and it can be bigger or smaller than iron atoms. Many alloys are produced to give a stronger metal. The presence of the other atoms (smaller or bigger) disrupts the symmetry of the layers and reduces the 'slip ability' of one layer next to another. The result is a stronger harder less malleable metal.
  4. The main point about using alloys is that you can make up, and try out, all sorts of different compositions until you find the one that best suits the required purpose in terms of tensile/compression strength, malleability, electrical conductivity or corrosion resistance etc.

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Revision notes information to help revise KS4 Science Additional Science Triple Award Separate Sciences GCSE/IGCSE/O level Chemistry Revision-Information Study Notes for revising for AQA GCSE Science, Edexcel GCSE Science/IGCSE Chemistry & OCR 21st Century Science, OCR Gateway Science WJEC/CBAC GCSE science-chemistry CCEA/CEA GCSE science-chemistry (and courses equal to US grades 8, 9, 10) basic aid notes for GCE Advanced Subsidiary Level AS Advanced Level A2 IB Revise AQA OCR Edexcel Salters CIE, CCEA/CEA & WJEC advanced level courses for pre-university students (equal to US grade 11 and grade 12 and Honours/honors level courses)


WHAT NEXT? - other pages to do with metals

 



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