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Brown's Chemistry - Chemical Bonding - Revision Notes
Part 5 Metallic Bonding,
Structure and Properties
Revision KS4 Science IGCSE/O level/GCSE
Chemistry Information Study Notes for revising for AQA GCSE Science, Edexcel
360Science/IGCSE Chemistry & OCR 21stC Science, OCR Gateway Science
(revise courses equal to US grades 9-10) Revision notes for GCE Advanced
Subsidiary Level AS Advanced Level A2 IB Revise AQA OCR Edexcel Salters CIE
revising courses for pre-university students (equal to US grade 11 and grade 12
and Honours/honors level courses)
Part 1 Introduction - why do atoms bond together?
& sub-index for Parts 2-5 (read 1st)
Part 2
Ionic Bonding - compounds and properties
Part 3
Covalent Bonding -small simple molecules and properties
Part 4
Covalent Bonding - macromolecules and giant covalent structures
Part 5 Metallic Bonding - structure and properties of metals
(this page)
Part 6 More advanced concepts for
advanced level chemistry (in preparation, BUT a lot on
intermolecular forces in Equilibria Part 8)
Part 5.
METALLIC BONDING
- structure and properties of metals
metal
bonding model element/alloys * physical properties of
metals
BONDING IN
METALS
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A
giant metallic lattice. The
crystal lattice of metals consists of ions
NOT atoms surrounded by a 'sea of electrons'
forming another type of giant lattice.
- The outer electrons
(-) from the
original metal atoms are free to move around between the positive
metal ions formed (+).
- These free or 'delocalised'
electrons are the 'electronic glue' holding the particles together.
- There is a strong
electrical force of attraction between these mobile
electrons (-) and the 'immobile' positive metal ions (+)
and this is the metallic bond.
- Metallic bonding is not
directional like covalent bonding, it is like ionic bonding in the
sense that the force of attraction between the positive metal ions
and the mobile electrons acts in every direction about the fixed
(immobile) metal ions.
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Explaining the physical
properties of metals
-
This strong bonding generally results
in dense, strong materials with high melting and boiling points.
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Metals are good conductors of electricity because
these 'free' electrons carry the charge of an electric current when a
potential difference (voltage!) is applied across a piece of metal.
-
Metals are also good conductors of heat.
This is also due to the free moving electrons. Non-metallic solids conduct
heat energy by hotter more strongly vibrating atoms, knocking against cooler
less strongly vibrating atoms to pass the particle kinetic energy on. In
metals, as well as this effect, the 'hot' high kinetic energy electrons move
around freely to transfer the particle kinetic energy more efficiently to
'cooler' atoms.
-
Typical metals also have a silvery surface
but remember this may be easily tarnished by corrosive oxidation in air and
water.
-
Unlike ionic solids, metals are very
malleable, they can be readily bent, pressed or hammered into shape. The
layers of atoms can slide over each other without fracturing
the structure (see below). The
reason for this is the mobility of the electrons. When planes of
metal atoms are 'bent' or slide the electrons can run in between the atoms and
maintain a strong bonding situation. This can't happen in ionic solids.
-
For more on the properties and uses of metals
see Transition Metals and Extra
Industrial Chemistry pages and the note and diagram below.
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Note
on Alloy Structure
- Shows the regular arrangement of the
atoms in a metal crystal and the white spaces show where the free
electrons are (yellow circles actually positive metal ions).
- Shows what happens when the metal is
stressed by a strong force. The layers of atoms can slide over each
other and the bonding is maintained as the mobile electrons keep in
contact with atoms, so the metal remains intact BUT a different
shape.
- Shows an alloy mixture. It is NOT a
compound but a physical mixing of a metal plus at least one other
material (shown by red circle, it can be another metal e.g. Ni, a
non-metal e.g. C or a compound of carbon or manganese, and it can be
bigger or smaller than iron atoms). Many alloys are produced to give
a stronger metal. The presence of the other atoms (smaller or
bigger) disrupts the symmetry of the layers and reduces the 'slip
ability' of one layer next to another. The result is a stronger
harder less malleable metal.
- The main point about using
alloys is that you can make up, and try out, all sorts of different
compositions until you find the one that best suits the required
purpose.
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| (thai) Doc Brown 's เคมี
-- พันธะเคมี -- ส่วนติดโครงสร้างโลหะ 5 และคุณสมบัติ ส่วนที่
5 โลหะ Bonding -- โครงสร้างและสมบัติของโลหะ (หน้านี้) *
(portuguese) Doc Brown de Química - ligação química - Notas
de Revisão Parte 5 Colagem Estrutura Metálica e Propriedades
Parte 5 Metallic Colagem estrutura e propriedades dos metais
elemento do modelo de ligação metal / ligas * propriedades
físicas dos metais * (indonesia) Doc Brown Kimia - Ikatan
Kimia - Catatan Revisi Bagian 5 Bonding metalik, Struktur
dan Properties Bagian 5 Metalik Bonding - struktur dan sifat
logam (halaman ini) bonding elemen logam model / paduan *
sifat fisik logam *
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